|
|
H+ + 2,5-Dihydroxybenzoate <=> CO2 + hydroquinone
|
4.1.1.46
o-pyrocatechuate decarboxylase
4.1.1.62
gentisate decarboxylase
|
–
–
|
K
|
|
BRENDA:
BR323
KEGG:
R02489
MetaCyc:
GENTISATE-DECARBOXYLASE-RXN
|
|
|
|
2,5-Dihydroxybenzoate + O2 <=> maleylpyruvate + H+
|
1.13.11.4
gentisate 1,2-dioxygenase
1.13.11.86
5-aminosalicylate 1,2-dioxygenase
|
–
–
|
BMK
|
|
BRENDA:
BR36757
KEGG:
R02656
MetaCyc:
GENTISATE-12-DIOXYGENASE-RXN
SABIO-RK:
2552
|
|
|
|
3-hydroxybenzoate + O2 + NADH + H+ <=> 2,5-Dihydroxybenzoate + H2O + NAD+
|
1.14.13.24
3-hydroxybenzoate 6-monooxygenase
|
–
|
MK
|
|
BRENDA:
BR40429
KEGG:
R02589
MetaCyc:
3-HYDROXYBENZOATE-6-MONOOXYGENASE-RXN
|
|
|
|
salicylate + O2 + NADH + H+ <=> 2,5-Dihydroxybenzoate + NAD+ + H2O
|
1.14.13.172
salicylate 5-hydroxylase
|
–
|
MK
|
|
BRENDA:
BR50516
KEGG:
R07709
MetaCyc:
RXN-10446
|
|
|
|
2,5-dihydroxybenzaldehyde + NADP+ + H2O <=> 2,5-Dihydroxybenzoate + NADPH + H+
|
1.2.1
1.2.1.5
aldehyde dehydrogenase [NAD(P)+]
|
–
–
|
|
|
BRENDA:
BS231673
MetaCyc:
RXN-15478
|
|
|
|
2,5-dihydroxybenzaldehyde + NAD+ <=> 2,5-Dihydroxybenzoate + NADH
|
1.2.1.29
aryl-aldehyde dehydrogenase
|
–
|
K
|
|
BRENDA:
BS189184
KEGG:
R02655
|
|
|
|
salicylate + NADPH + H+ + O2 <=> 2,5-Dihydroxybenzoate + NADP+ + H2O
|
1.14.13.172
salicylate 5-hydroxylase
|
–
|
K
|
|
BRENDA:
BS422071
KEGG:
R07710
|
|
|
|
2,5-dihydroxybenzoyl-CoA + H2O <=> 2,5-Dihydroxybenzoate + CoA + H+
|
3.1.2.23
4-hydroxybenzoyl-CoA thioesterase
|
–
|
M
|
|
MetaCyc:
RXN-11741
SABIO-RK:
12794
|
|
|
|
2,5-Dihydroxybenzoate + H2O2 <=> 2,5-dihydroxybenzaldehyde + O2 + H2O
|
1.2.3.1
aldehyde oxidase
|
–
|
K
|
|
KEGG:
R02657
|
|
|
|
5-sulfosalicylic_acid + O2 <=> 2,5-Dihydroxybenzoate + sulfate
|
not assigned
|
–
|
K
|
|
KEGG:
R07686
|
|
|
|
3-hydroxybenzoyl-CoA + O2 + reduced_acceptor <=> 2,5-Dihydroxybenzoate + CoA + H+ + acceptor
|
not assigned
|
–
|
M
|
|
MetaCyc:
R246-RXN
|
|
|
|
UDP-glucose + 2,5-Dihydroxybenzoate <=> 2,5-dihydroxybenzoate_5-O-beta-D-glucoside + UDP + H+
|
2.4.1
|
–
|
M
|
|
MetaCyc:
RXN-11705
|
|
|
|
2,5-Dihydroxybenzoate + UDP-D-xylose <=> gentisate_5-O-beta-D-xylopyranoside + UDP + H+
|
2.4.1
|
–
|
M
|
|
MetaCyc:
RXN18C3-51
|
|
|
|
2,5-Dihydroxybenzoate + H+ <=> 2,5-Dihydroxybenzoate + H+
|
not assigned
|
–
|
|
|
MetaCyc:
TRANS-RXN18HP-97
|
|
|
|
2,5-dihydroxybenzaldehyde + H2O + 2,6-dichlorophenolindophenol <=> 2,5-Dihydroxybenzoate + reduced_2,6-dichlorophenolindophenol
|
1.2.99.7
aldehyde dehydrogenase (FAD-independent)
|
–
|
|
|
BRENDA:
BS438703
|
|
|
|
4-coumaroyl-CoA + 2,5-Dihydroxybenzoate <=> CoA + 5-O-(4-coumaroyl)gentisate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS435128
|
|
|
|
2,5-Dihydroxybenzoate + NADH + O2 <=> Hydroxyquinol + CO2 + H2O + NAD+
|
1.14.13.1
salicylate 1-monooxygenase
|
–
|
|
|
BRENDA:
BS257936
|
|
|
|
2,5-Dihydroxybenzoate + NADH + H+ + O2 <=> Hydroxyquinol + NAD+ + H2O + CO2
|
1.14.13.1
salicylate 1-monooxygenase
|
–
|
|
|
BRENDA:
BS440929
|
|
|
|
3-hydroxybenzoate + NADPH + O2 <=> 2,5-Dihydroxybenzoate + NADP+ + H2O
|
1.14.13.24
3-hydroxybenzoate 6-monooxygenase
|
–
|
B
|
|
BRENDA:
BS386123
|
|
|
|
ATP + 2,5-Dihydroxybenzoate <=> diphosphate + (2,5-dihydroxybenzoyl)adenylate
|
2.7.7.58
(2,3-dihydroxybenzoyl)adenylate synthase
|
–
|
|
|
BRENDA:
BS358664
|
|
|
|
2,5-dihydroxybenzoic_acid_methyl_ester + H2O <=> methanol + 2,5-Dihydroxybenzoate
|
3.1.1.20
tannase
|
–
|
|
|
BRENDA:
BS430408
|
|